Effect of the Main Operating Variables on Efficiency of Treating Industrial Flue Gases Using Potash and Yellow Phosphorus

Authors

  • Montaser Alzaky
  • Rawya Adam Basheer
  • Tomadir Ibrahim
  • Samah SirElhkateem Ahmed
  • Rawia Siddig
  • Eltayeb Asal
  • Mohamed Magzoub GariebAllah

DOI:

https://doi.org/10.54388/jkues.v2i4.219

Keywords:

Flue gases treatment, Yellow Phosphorus, Potash, Simultaneous removal, SOX and NOX removal efficiency, Reaction mechanism.

Abstract

Fossil energy is considered as an important source of energy used in different types of industries. However it emits a great amount of flue gases. Some components of flue gases such as SOx and NOx can cause negative environmental impacts. Acid rains, increasing greenhouse effects and causing humans health problem (for Respiratory system) are some of them. A bench scale experiments using: 2900 ppm SOx, 550 ppmNOx , 1L deionize water, 0.5 g P4, and 10 g MOP were conducted in order to investigate the effects of operating conditions in removing process. These conditions are: emulsion temperature, yellow phosphorus weight, and the emulsion stirring intensity. Optimum conditions for removing process are (55oc, 1743 rpm, using 0.5 g P4). It was also observed that emulsion’s pH and oxygen concentration are declined with reaction time, but they have a positive correlations with removing efficiency, whereas efficiency increasing when rising emulsions temperature and stirring intensity. The obtained results identified the optimum conditions to get the highest efficiency for removing SOx and NOx from flue gases to eliminate their environmental impact

References

V. C. Srivastava, “An evaluation of desulfurization technologies for sulfur removal from liquid fuels,” Rsc Advances, vol. 2, no. 3, pp. 759–783, 2012.

S. Li, J. Yang, C. Wang, D. Xie, Y. Luo, K. Li, D. He, and Y. Mei, “Removal of no x from flue gas using yellow phosphorus and phosphate

slurry as adsorbent,” Energy & Fuels, vol. 32, no. 4, pp. 5279–5288,2018.

M. A. M. Alzaky, S. S. E. Ahmed, R. A. Basheer, R. Siddig, T. A. Ibraheem, M. Kashif, F. Wang, H. Lu, J. Tan, and D. Li, “Yellow phosphorus and potash for sox and nox removal,” Environmental Technology,pp. 1–9, 2021.

R. Li, T. Liu, Y. Zhang, and J. Huang, “Mechanism of novel k2so4/kcl composite roasting additive for strengthening vanadium extraction from vanadium–titanium magnetite concentrate,” Minerals, vol. 8, no. 10,p. 426, 2018.

Y. Zhao, S. Wang, L. Duan, Y. Lei, P. Cao, and J. Hao, “Primary air pollutant emissions of coal-fired power plants in china: Current

status and future prediction,” Atmospheric Environment, vol. 42, no. 36, pp. 8442–8452, 2008.

C. R. Dempsey and E. T. Oppelt, “Incineration of hazardous waste: a critical review update,” Air & Waste, vol. 43, no. 1, pp. 25–73, 1993.

M. A. M. Alzaky, S. S. E. Ahmed, R. A. Basheer, R. Siddig, T. A. Ibraheem, M. Kashif, F. Wang, H. Lu, J. Tan, and D. Li, “Yellow phosphorus and potash for sox and nox removal,” Environmental Technology, pp. 1–9, 2021.

H. Cordes and W. Witschel, “Einige aussagen zur oxydation des phosphors,” Zeitschrift fur Physikalische Chemie ¨ , vol. 46, no. 1 2, pp. 35–48, 1965.

J. Ding, Q. Zhong, S. Zhang, F. Song, and Y. Bu, “Simultaneous removal of nox and so2 from coal-fired flue gas by catalytic oxidation-removal process with h2o2,” Chemical Engineering Journal, vol. 243, pp. 176–182, 2014.

E. Kontturi, P. Laaksonen, M. B. Linder, A. H. Groschel, O. J. Rojas, and ¨O. Ikkala, “Advanced materials through assembly of nanocelluloses,” Advanced Materials, vol. 30, no. 24, p. 1703779, 2018.

Z. Xue, H. Chen, and M. Zhao, “Combined removal of nox and so2 from flue gas at low temperature,” in E3S Web of Conferences, vol. 53, p. 04038, EDP Sciences, 2018.

S. Li, J. Yang, C. Wang, D. Xie, Y. Luo, K. Li, D. He, and Y. Mei, “Removal of no x from flue gas using yellow phosphorus and phosphate

slurry as adsorbent,” Energy & Fuels, vol. 32, no. 4, pp. 5279–5288, 2018.

Y. Sun, X. Hong, T. Zhu, X. Guo, and D. Xie, “The chemical behaviors of nitrogen dioxide absorption in sulfite solution,” Applied Sciences, vol. 7, no. 4, p. 377, 2017

Downloads

Published

2024-04-25

How to Cite

Alzaky, M. ., Basheer, . R. A. ., Ibrahim, T. ., Ahmed, . S. S. ., Siddig, . R. ., Asal, E. ., & GariebAllah, . M. M. . (2024). Effect of the Main Operating Variables on Efficiency of Treating Industrial Flue Gases Using Potash and Yellow Phosphorus. Journal of Karary University for Engineering and Science, 2(4). https://doi.org/10.54388/jkues.v2i4.219

Issue

Section

Chemical Science and Engineering

Similar Articles

<< < 1 2 3 4 > >> 

You may also start an advanced similarity search for this article.